Evaluation of Parameters in the Removal of Linear Alkylbenzene Sulfonate Anionic Surfactant Using Electrocoagulation

The objective of the present investigation was to construct an electrocoagulation cell in a batch system and to evaluate its capacity to remove the anionic surfactant of the linear alkylbenzene sulfonate (LAS), which is present in gray water determining the effect of the type of electrodes (Al or Fe...

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Main Authors: Villabona-Ortíz, Angel, Tejada-Tovar, Candelaria, De-La-Rosa-Jiménez, Lenis
Format: Online
Language:eng
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Published: Universidad Pedagógica y Tecnológica de Colombia 2020
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Online Access:https://revistas.uptc.edu.co/index.php/ingenieria/article/view/11570
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author Villabona-Ortíz, Angel
Tejada-Tovar, Candelaria
De-La-Rosa-Jiménez, Lenis
author_facet Villabona-Ortíz, Angel
Tejada-Tovar, Candelaria
De-La-Rosa-Jiménez, Lenis
author_sort Villabona-Ortíz, Angel
collection OJS
description The objective of the present investigation was to construct an electrocoagulation cell in a batch system and to evaluate its capacity to remove the anionic surfactant of the linear alkylbenzene sulfonate (LAS), which is present in gray water determining the effect of the type of electrodes (Al or Fe), distance between electrodes (1, 1.5 and 2 cm) and voltages (10, 15 and 20 V). The experimental tests were carried out for 20 min. The dimensions of the short wave electrolysis cell built in glass were 26 cm long, 7 cm wide and 12 cm high, with 10 electrodes of 12x6 cm supported by a PVC structure. The concentration of LAS in the solution was determined by employing UV-Vis spectrometry applying the Methylene Blue Active Substances (MBAS) method. A higher removal of 65.55% was obtained when aluminum electrodes were used, and 69.11% with iron electrodes a separation of 1.5 cm and a voltage of 20 V, presenting less change in pH, conductivity, and energy consumption when using the Al3 electrode. When evaluating the effect of time at the best experimental configuration (Al, 1.5 cm, 20 V) it was established that the removal efficiency increased to 75.13% in 60 min. Electrocoagulation with aluminum electrodes is presented as an efficient alternative for the removal of LAS in solution.
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spelling oai:oai.revistas.uptc.edu.co:article-115702021-08-03T19:28:23Z Evaluation of Parameters in the Removal of Linear Alkylbenzene Sulfonate Anionic Surfactant Using Electrocoagulation Evaluación de parámetros en la remoción de surfactante aniónico tipo Alquilbenceno sulfonato lineal usando electrocoagulación Villabona-Ortíz, Angel Tejada-Tovar, Candelaria De-La-Rosa-Jiménez, Lenis Emerging contaminants shortwave electrolysis electrochemistry LAS contaminantes emergentes electrólisis de onda corta electroquímica LAS The objective of the present investigation was to construct an electrocoagulation cell in a batch system and to evaluate its capacity to remove the anionic surfactant of the linear alkylbenzene sulfonate (LAS), which is present in gray water determining the effect of the type of electrodes (Al or Fe), distance between electrodes (1, 1.5 and 2 cm) and voltages (10, 15 and 20 V). The experimental tests were carried out for 20 min. The dimensions of the short wave electrolysis cell built in glass were 26 cm long, 7 cm wide and 12 cm high, with 10 electrodes of 12x6 cm supported by a PVC structure. The concentration of LAS in the solution was determined by employing UV-Vis spectrometry applying the Methylene Blue Active Substances (MBAS) method. A higher removal of 65.55% was obtained when aluminum electrodes were used, and 69.11% with iron electrodes a separation of 1.5 cm and a voltage of 20 V, presenting less change in pH, conductivity, and energy consumption when using the Al3 electrode. When evaluating the effect of time at the best experimental configuration (Al, 1.5 cm, 20 V) it was established that the removal efficiency increased to 75.13% in 60 min. Electrocoagulation with aluminum electrodes is presented as an efficient alternative for the removal of LAS in solution. El objetivo de la presente investigación fue construir una celda de electrocoagulación en sistema por lotes y evaluar su capacidad de remover el surfactante aniónico de tipo Alquilbenceno sulfonato lineal (LAS) presente en aguas grises determinando el efecto del tipo de electrodos (Al o Fe), distancia entre electrodos (1, 1.5 y 2 cm) y voltajes de (10, 15 y 20 V). Los ensayos experimentales se realizaron durante 20 min. Las dimensiones de la celda electrólisis de onda corta construida en vidrio fueron 26 cm de largo, 7 cm de ancho y 12 cm de alto, con 10 electrodos de 12x6 cm sostenidos por una estructura de PVC. Se determinó la concentración de LAS en la solución mediante espectometria UV-Vis aplicando el método el método de Sustancias Activas al Azul de Metileno (SAAM). Se obtuvo una mayor remoción del 65.55% cuando se usó electrodos de aluminio, y 69.11% con electrodos de hierro una separación de 1.5 cm y un voltaje de 20 V, presentándose menor cambio en el pH, conductividad y consumo energético al usar el electrodo de Al3. Al evaluar el efecto del tiempo a la mejor configuración experimental (Al, 1.5 cm, 20 V) se estableció que la eficiencia de remoción aumentó a 75.13% en 60 min. Se presenta la electrocoagulación con electrodos de aluminios como una alternativa eficiente para la remoción de LAS en solución. Universidad Pedagógica y Tecnológica de Colombia 2020-12-29 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf application/pdf application/xml https://revistas.uptc.edu.co/index.php/ingenieria/article/view/11570 10.19053/01211129.v30.n55.2021.11570 Revista Facultad de Ingeniería; Vol. 30 No. 55 (2021): January-March 2021 (Continuous Publication); e11570 Revista Facultad de Ingeniería; Vol. 30 Núm. 55 (2021): Enero-Marzo 2021 (Publicación Continua); e11570 2357-5328 0121-1129 eng spa https://revistas.uptc.edu.co/index.php/ingenieria/article/view/11570/10034 https://revistas.uptc.edu.co/index.php/ingenieria/article/view/11570/10035 https://revistas.uptc.edu.co/index.php/ingenieria/article/view/11570/10781 Copyright (c) 2021 Angel Villabona-Ortíz, M.Sc., Candelaria Tejada-Tovar, M.Sc., Lenis De-La-Rosa-Jiménez http://creativecommons.org/licenses/by/4.0
spellingShingle Emerging contaminants
shortwave electrolysis
electrochemistry
LAS
contaminantes emergentes
electrólisis de onda corta
electroquímica
LAS
Villabona-Ortíz, Angel
Tejada-Tovar, Candelaria
De-La-Rosa-Jiménez, Lenis
Evaluation of Parameters in the Removal of Linear Alkylbenzene Sulfonate Anionic Surfactant Using Electrocoagulation
title Evaluation of Parameters in the Removal of Linear Alkylbenzene Sulfonate Anionic Surfactant Using Electrocoagulation
title_alt Evaluación de parámetros en la remoción de surfactante aniónico tipo Alquilbenceno sulfonato lineal usando electrocoagulación
title_full Evaluation of Parameters in the Removal of Linear Alkylbenzene Sulfonate Anionic Surfactant Using Electrocoagulation
title_fullStr Evaluation of Parameters in the Removal of Linear Alkylbenzene Sulfonate Anionic Surfactant Using Electrocoagulation
title_full_unstemmed Evaluation of Parameters in the Removal of Linear Alkylbenzene Sulfonate Anionic Surfactant Using Electrocoagulation
title_short Evaluation of Parameters in the Removal of Linear Alkylbenzene Sulfonate Anionic Surfactant Using Electrocoagulation
title_sort evaluation of parameters in the removal of linear alkylbenzene sulfonate anionic surfactant using electrocoagulation
topic Emerging contaminants
shortwave electrolysis
electrochemistry
LAS
contaminantes emergentes
electrólisis de onda corta
electroquímica
LAS
topic_facet Emerging contaminants
shortwave electrolysis
electrochemistry
LAS
contaminantes emergentes
electrólisis de onda corta
electroquímica
LAS
url https://revistas.uptc.edu.co/index.php/ingenieria/article/view/11570
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