Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions
Sulfonated alumina was synthetized and tested for the first time in furfural valorization through a multicomponent reaction for the preparation of a nitrogenated heterocyclic compound containing the furan substructure. Ten polysubstituted heterocycles, belonging to the dihydropyrimidinones (thiones)...
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| Format: | Online |
| Language: | spa |
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Universidad Pedagógica y Tecnológica de Colombia
2021
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| Online Access: | https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12821 |
| _version_ | 1801706350489632768 |
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| author | Nope, Eliana Ruiz, D. Sathicq, Angel Romanelli, Gustavo |
| author_facet | Nope, Eliana Ruiz, D. Sathicq, Angel Romanelli, Gustavo |
| author_sort | Nope, Eliana |
| collection | OJS |
| description | Sulfonated alumina was synthetized and tested for the first time in furfural valorization through a multicomponent reaction for the preparation of a nitrogenated heterocyclic compound containing the furan substructure. Ten polysubstituted heterocycles, belonging to the dihydropyrimidinones (thiones) and 1,4-dihydropyridines, were obtained with very good yields (70% – 85%) using the tandem methodology and green reaction conditions. The catalyst was easily separated from the reaction medium, giving a high yield in the reusability studies. Green metrics were analyzed in order to consider the reaction suitability. |
| format | Online |
| id | oai:oai.revistas.uptc.edu.co:article-12821 |
| institution | Revista Ciencia en Desarrollo |
| language | spa |
| publishDate | 2021 |
| publisher | Universidad Pedagógica y Tecnológica de Colombia |
| record_format | ojs |
| spelling | oai:oai.revistas.uptc.edu.co:article-128212021-12-14T02:35:17Z Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions Alúmina sulfonada: un catalizador adecuado para la valorización de componentes básicos de biomasa furfural a través de reacciones multicomponente. Nope, Eliana Ruiz, D. Sathicq, Angel Romanelli, Gustavo valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdes furfural valorization, sulfonated silica, multicomponent reaction, nitrogenated heterocyclic compounds, green metrics analysis Sulfonated alumina was synthetized and tested for the first time in furfural valorization through a multicomponent reaction for the preparation of a nitrogenated heterocyclic compound containing the furan substructure. Ten polysubstituted heterocycles, belonging to the dihydropyrimidinones (thiones) and 1,4-dihydropyridines, were obtained with very good yields (70% – 85%) using the tandem methodology and green reaction conditions. The catalyst was easily separated from the reaction medium, giving a high yield in the reusability studies. Green metrics were analyzed in order to consider the reaction suitability. La alúmina sulfonada se sintetizó y ensayó por primera vez en la valorización del furfural mediante una reacción multicomponente para la preparación de un compuesto heterocíclico nitrogenado que contiene la subestructura de furano. Se obtuvieron diez heterociclos polisustituidos, pertenecientes a las dihidropirimidinonas (tiones) y 1,4-dihidropiridinas, con muy buenos rendimientos (70% - 85%) utilizando la metodología tándem y las condiciones de reacción verde. El catalizador se separó fácilmente del medio de reacción, dando un alto rendimiento en los estudios de reutilización. Se analizaron las métricas verdes para considerar la idoneidad de la reacción. Universidad Pedagógica y Tecnológica de Colombia 2021-05-10 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12821 10.19053/01217488.v12.n1.2021.12821 Ciencia En Desarrollo; Vol. 12 No. 1 (2021): Vol 12, Núm.1 (2021): Enero-Junio; 113-123 Ciencia en Desarrollo; Vol. 12 Núm. 1 (2021): Vol 12, Núm.1 (2021): Enero-Junio; 113-123 2462-7658 0121-7488 spa https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12821/10697 Derechos de autor 2021 CIENCIA EN DESARROLLO |
| spellingShingle | valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdes furfural valorization, sulfonated silica, multicomponent reaction, nitrogenated heterocyclic compounds, green metrics analysis Nope, Eliana Ruiz, D. Sathicq, Angel Romanelli, Gustavo Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| title | Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| title_alt | Alúmina sulfonada: un catalizador adecuado para la valorización de componentes básicos de biomasa furfural a través de reacciones multicomponente. |
| title_full | Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| title_fullStr | Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| title_full_unstemmed | Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| title_short | Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| title_sort | sulfonated alumina a suitable catalyst for furfural biomass building block valorization through multicomponent reactions |
| topic | valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdes furfural valorization, sulfonated silica, multicomponent reaction, nitrogenated heterocyclic compounds, green metrics analysis |
| topic_facet | valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdes furfural valorization, sulfonated silica, multicomponent reaction, nitrogenated heterocyclic compounds, green metrics analysis |
| url | https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12821 |
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