Purification of the carbon dioxide emitted by gas treatment plants

In natural gas plants, the carbon dioxide (CO2) traveling in the extracted stream is separated and released to the atmosphere. This stream also contains hydrogen sulfide (H2S), water and hydrocarbons. The purpose of this investigation was to design a process to purify this CO2 stream, to it...

Full description

Bibliographic Details
Main Authors: Gámez, Nancy, Cobo, Martha
Format: Online
Language:spa
Published: Universidad Pedagógica y Tecnológica de Colombia 2018
Subjects:
Online Access:https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/7392
_version_ 1801706340967514112
author Gámez, Nancy
Cobo, Martha
author_facet Gámez, Nancy
Cobo, Martha
author_sort Gámez, Nancy
collection OJS
description In natural gas plants, the carbon dioxide (CO2) traveling in the extracted stream is separated and released to the atmosphere. This stream also contains hydrogen sulfide (H2S), water and hydrocarbons. The purpose of this investigation was to design a process to purify this CO2 stream, to its further use in the food industry. There, the CO2 can be employed in carbonated drinks and as supercritical fluid; requiring a purity higher than 99.95 mol%. Therefore, a real flow of 3454 ton/year CO2 was selected as case of study, which is emitted in a gas treatment plant located in Neiva, Colombia. This stream was simulated in ProMax and subjected to chemical absorption with methyl diethanolamine (MDEA), to a dehydration with diethylene glycol combined with molécular sieve, to a Ryan-Holmes cryogenic process for removing light components (methane and ethane) and their combinations. The combination of the three processes allowed us for a 99.95% CO2 recovery and a 99.99 mol% CO2 purity, requiring capital expenses (CAPEX) of USD 412.323 or 53 USD/tCO2. This CO2 could be commercialized at sell prices as high as 5000 USD/tCO2 to the food industry. In addition, the combination of the two first processes delivered a CAPEX of 37 USD/tCO2 with a 99.85 mol% CO2 purity, suitable for other applications requiring less purity in the food industry or improved oil recovery.
format Online
id oai:oai.revistas.uptc.edu.co:article-7392
institution Revista Ciencia en Desarrollo
language spa
publishDate 2018
publisher Universidad Pedagógica y Tecnológica de Colombia
record_format ojs
spelling oai:oai.revistas.uptc.edu.co:article-73922022-06-15T17:03:20Z Purification of the carbon dioxide emitted by gas treatment plants Purificación de dióxido de carbono emitido en las plantas de gas natural Gámez, Nancy Cobo, Martha Calentamiento global CAPEX Costos de inversión Captura y uso de carbono Simulación de procesos. Global warming; CAPEX; Capital expenses; Carbon capture and utilization (CCU); Process simulation In natural gas plants, the carbon dioxide (CO2) traveling in the extracted stream is separated and released to the atmosphere. This stream also contains hydrogen sulfide (H2S), water and hydrocarbons. The purpose of this investigation was to design a process to purify this CO2 stream, to its further use in the food industry. There, the CO2 can be employed in carbonated drinks and as supercritical fluid; requiring a purity higher than 99.95 mol%. Therefore, a real flow of 3454 ton/year CO2 was selected as case of study, which is emitted in a gas treatment plant located in Neiva, Colombia. This stream was simulated in ProMax and subjected to chemical absorption with methyl diethanolamine (MDEA), to a dehydration with diethylene glycol combined with molécular sieve, to a Ryan-Holmes cryogenic process for removing light components (methane and ethane) and their combinations. The combination of the three processes allowed us for a 99.95% CO2 recovery and a 99.99 mol% CO2 purity, requiring capital expenses (CAPEX) of USD 412.323 or 53 USD/tCO2. This CO2 could be commercialized at sell prices as high as 5000 USD/tCO2 to the food industry. In addition, the combination of the two first processes delivered a CAPEX of 37 USD/tCO2 with a 99.85 mol% CO2 purity, suitable for other applications requiring less purity in the food industry or improved oil recovery. En las plantas de extracción de gas natural (GN), el dióxido de carbono (CO2) que viaja en la corriente extraída se separa y se libera a la atmósfera, acompañado de ácido sulfídrico (H2S), agua e hidrocarburos. El objetivo de esta investigación fue diseñar un proceso para purificar esta corriente de CO2, para su posterior uso en la industria alimenticia, donde el CO2 se puede usar en bebidas carbonatadas y como fluido supercrítico; requiriendo una pureza superior a 99,95% mol. Para ello, se seleccionó como caso de estudio un flujo real de 3454 ton/año de CO2 emitido por una planta de gas natural localizada en Neiva, Colombia y se simuló en ProMax. Se simularon la absorción química con metildietanolamina (MDEA), deshidratación con trietilenglicol (TEG) combinada con tamiz molecular, procesos criogénicos de Ryan Holmes y sus combinaciones. La combinación de los tres procesos permitió una recuperación de 99,95% de CO2 con una pureza del 99,99 %mol, requiriendo una inversión total de USD 412.323 o 53 USD/tCO2. Esta CO2 podría ser comercializado a valores superiores a 5000 USD/tCO2 para la industria alimenticia. Además, la combinación de los dos primeros procesos arrojó costos de 37 USD/tCO2, produciendo una pureza de CO2 de 99,85 %mol apto para otras aplicaciones. Universidad Pedagógica y Tecnológica de Colombia 2018-07-04 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Simulación de procesos application/pdf https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/7392 10.19053/01217488.v9.n2.2018.7392 Ciencia En Desarrollo; Vol. 9 No. 2 (2018): Vol 9, Núm. 2 (2018): Vol 9, Núm 2(2018): Julio- Diciembre; 137-148 Ciencia en Desarrollo; Vol. 9 Núm. 2 (2018): Vol 9, Núm. 2 (2018): Vol 9, Núm 2(2018): Julio- Diciembre; 137-148 2462-7658 0121-7488 spa https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/7392/7266 Derechos de autor 2018 CIENCIA EN DESARROLLO
spellingShingle Calentamiento global
CAPEX
Costos de inversión
Captura y uso de carbono
Simulación de procesos.
Global warming; CAPEX; Capital expenses; Carbon capture and utilization (CCU); Process simulation
Gámez, Nancy
Cobo, Martha
Purification of the carbon dioxide emitted by gas treatment plants
title Purification of the carbon dioxide emitted by gas treatment plants
title_alt Purificación de dióxido de carbono emitido en las plantas de gas natural
title_full Purification of the carbon dioxide emitted by gas treatment plants
title_fullStr Purification of the carbon dioxide emitted by gas treatment plants
title_full_unstemmed Purification of the carbon dioxide emitted by gas treatment plants
title_short Purification of the carbon dioxide emitted by gas treatment plants
title_sort purification of the carbon dioxide emitted by gas treatment plants
topic Calentamiento global
CAPEX
Costos de inversión
Captura y uso de carbono
Simulación de procesos.
Global warming; CAPEX; Capital expenses; Carbon capture and utilization (CCU); Process simulation
topic_facet Calentamiento global
CAPEX
Costos de inversión
Captura y uso de carbono
Simulación de procesos.
Global warming; CAPEX; Capital expenses; Carbon capture and utilization (CCU); Process simulation
url https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/7392
work_keys_str_mv AT gameznancy purificationofthecarbondioxideemittedbygastreatmentplants
AT cobomartha purificationofthecarbondioxideemittedbygastreatmentplants
AT gameznancy purificaciondedioxidodecarbonoemitidoenlasplantasdegasnatural
AT cobomartha purificaciondedioxidodecarbonoemitidoenlasplantasdegasnatural