Evaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá)

1 recurso en línea (105 páginas) : figuras, tablas.

Bibliographic Details
Main Author:	Lara Sandoval, Adriana Elizabeth
Other Authors:	Chaparro Acuña, Sandra Patricia
Format:	Trabajo de grado - Maestría
Language:	spa
Published:	Universidad Pedagógica y Tecnológica de Colombia 2019
Subjects:	Residuos de plaguicidas - Estudio de casos Persistencia de los plaguicidas Maestría en Química - Tesis y disertaciones académicas Agrosavia
Online Access:	http://repositorio.uptc.edu.co/handle/001/2586

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author	Lara Sandoval, Adriana Elizabeth
author2	Chaparro Acuña, Sandra Patricia
author_facet	Chaparro Acuña, Sandra Patricia Lara Sandoval, Adriana Elizabeth
author_sort	Lara Sandoval, Adriana Elizabeth
collection	DSpace
description	1 recurso en línea (105 páginas) : figuras, tablas.
format	Trabajo de grado - Maestría
id	repositorio.uptc.edu.co-001-2586
institution	Repositorio Institucional UPTC
language	spa
publishDate	2019
publisher	Universidad Pedagógica y Tecnológica de Colombia
record_format	dspace
spelling	repositorio.uptc.edu.co-001-25862023-03-14T15:43:02Z Evaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá) Lara Sandoval, Adriana Elizabeth Chaparro Acuña, Sandra Patricia Residuos de plaguicidas - Estudio de casos Persistencia de los plaguicidas Maestría en Química - Tesis y disertaciones académicas Agrosavia 1 recurso en línea (105 páginas) : figuras, tablas. Electrochemical methods for of glyphosate, paraquat, methomyl, carbofuran and mancozeb determination were validated for quantification in potato. The study was conducted using a voltammetric analyzer as supporting electrolyte Britton-Robinson buffer solution, the working electrode of glassy carbon, Ag / AgCl as reference electrode and platinum as counter electrode. Pesticides were extracted by solid-liquid partition method. Validation was carried out by two analysts who evaluated six batches consisting of two natural samples, two standard and two spiked or fortified samples. The methods showed no significant difference generating accurate and reliable results for the quantification of pesticides in samples of potato with a precision (%) and accuracy (%) of: 86.23 and 94.11 glyphosate, paraquat 86,04 and 96, 90, 85.93 and 83.016 methomyl, carbofuran 88.63 and 95.56 and 87.65 and 88.39 mancozeb, with a confidence level of 95%. The detection and quantification limits for the compounds were: 0.074 ppm and 0.19 ppm for glyphosate, 0.05 ppm and 0.55 ppm for paraquat, 0.12 ppm and 0.32 ppm for methomyl, 0.5 ppm and 1.98 ppm for carbofuran and 0.015 ppm and 0.076 ppm for mancozeb. Control charts were developed to evaluate the performance of validated methods and no value exceeded the warning limits. 100 samples collected in Ventaquemada village (Boyacá) were evaluated and the results state that none of the samples exceeded the maximum residue limit (MRL) of glyphosate (15 mg / kg) and mancozeb (0.2 mg / kg), 97 paraquat exceeded the MRL (0.05 mg / kg), 100 exceeded the MRL carbofuran (0.2 mg / kg) and methomyl not detected in any of the samples. In conclusion, paraquat herbicide and insecticide carbofuran are commonly used in this village to control weeds and insects, like the fungicide mancozeb, which is not used so indiscriminately as the previous two. Los métodos electroquímicos para la determinación de glifosato, paraquat, metomil, carbofurano y mancozeb fueron validados para su cuantificación en papa. El estudio fue llevado a cabo en un analizador voltamperométrico usando como electrolito de soporte solución buffer Britton-Robinson, electrodo de trabajo de carbón vítreo, Ag/AgCl como electrodo de referencia y platino como electrodo auxiliar. Los plaguicidas en papa fueron extraídos por reparto sólido-líquido. La validación fue llevada a cabo por dos analistas quienes evaluaron seis lotes compuestos por dos muestras naturales, dos estándares y dos muestras adicionadas o fortificadas. Los métodos no presentaron diferencia significativa generando resultados precisos y confiables para la cuantificación de los plaguicidas en muestras de papa con una precisión (%) y exactitud (%) de: glifosato 86,23 y 94,11, paraquat 86,04 y 96,90, metomil 85,93 y 83,016, carbofurano 88,63 y 95,56 y mancozeb 87,65 y 88,39, con un nivel de confiabilidad del 95%. Los límites de detección y cuantificación para los compuestos fueron: 0,074 ppm y 0,19 ppm para glifosato, 0,05 ppm y 0,55 ppm para paraquat, 0,12 ppm y 0,32 ppm para metomil, 0,5 ppm y 1,98 ppm para carbofurano y 0,015 ppm y 0,076 ppm para mancozeb. Se elaboraron cartas control para evaluar el desempeño de los métodos validados y ningún valor sobrepasó los límites de advertencia. Se evaluaron 100 muestras recolectadas en el municipio de Ventaquemada (Boyacá) y los resultados exponen que ninguna de las muestras excedieron el Límite Máximo Residual (LMR) de glifosato (15 mg/kg) y mancozeb (0,2 mg/kg), 97 sobrepasaron el LMR de paraquat (0,05 mg/kg), 100 excedieron el LMR de carbofurano (0,2 mg/kg) y no se detectó metomil en ninguna de las muestras. En conclusión, el herbicida paraquat y el insecticida carbofurano son los plaguicidas más usados en este municipio para el control de malezas e insectos, al igual que el fungicida mancozeb, el cual no se usa tan indiscriminadamente como los dos anteriores. Bibliografía y webgrafía : páginas 67-81. Maestría Magíster en Química 2019-05-10T22:12:17Z 2019-05-10T22:12:17Z 2015 Trabajo de grado - Maestría http://purl.org/coar/resource_type/c_bdcc info:eu-repo/semantics/masterThesis info:eu-repo/semantics/publishedVersion Text https://purl.org/redcol/resource_type/TM http://purl.org/coar/version/c_970fb48d4fbd8a85 Lara Sandoval, A. E. (2015). Evaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá). (Tesis de Maestría). Universidad Pedagógica y Tecnológica de Colombia, Tunja. http://repositorio.uptc.edu.co/handle/001/2586 http://repositorio.uptc.edu.co/handle/001/2586 spa M. R. Jan, J. Shah, M. Muhammad, and B. 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spellingShingle	Residuos de plaguicidas - Estudio de casos Persistencia de los plaguicidas Maestría en Química - Tesis y disertaciones académicas Agrosavia Lara Sandoval, Adriana Elizabeth Evaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá)
title	Evaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá)
title_full	Evaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá)
title_fullStr	Evaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá)
title_full_unstemmed	Evaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá)
title_short	Evaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá)
title_sort	evaluacion de la residualidad de plaguicidas en papa solanum tuberosum cultivada en ventaquemada boyaca
topic	Residuos de plaguicidas - Estudio de casos Persistencia de los plaguicidas Maestría en Química - Tesis y disertaciones académicas Agrosavia
url	http://repositorio.uptc.edu.co/handle/001/2586
work_keys_str_mv	AT larasandovaladrianaelizabeth evaluaciondelaresidualidaddeplaguicidasenpapasolanumtuberosumcultivadaenventaquemadaboyaca